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ISO DIS 19702 2014 Edition, April 13, 2014 GUIDANCE FOR SAMPLING AND ANALYSIS OF TOXIC GASES AND VAPOURS IN FIRE EFFLUENTS USING FOURIER TRANSFORM INFRARED SPECTROSCOPY (FTIR)
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Availability date: 07/14/2021
Description / Abstract:
This International Standard specifies requirements and makes
recommendations for sampling systems for use in small and
large-scale fire tests, for the selection of parameters and use of
the FTIR instrument itself and for collection and use of
calibration spectra.
The primary purpose of the methods is to measure the
concentrations of chemical species in fire effluents which may be
used to:
a. provide data for use in combustion toxicity assessment
without requiring biological studies;
b. allow the calculation of yield data in fire characterisation
studies;
c. provide data for use in mathematical modelling of hazard to
life from the fire effluent by characterising the effluent
composition generated by physical fire models;
d. characterise the effluent composition of small scale physical
models and larger scale fires for comparative purposes;
e. assist in the validation of numerical fire models;
f. set the conditions for exposure in biological studies if
required;
g. monitor biological studies where used; and
h. assist in the interpretation of biological studies where
used.
This International Standard specifies principles of sampling and
methods for the individual analysis, in fire effluents, of airborne
concentrations of carbon monoxide (CO), carbon dioxide
(CO2), hydrogen cyanide (HCN), hydrogen chloride (HCl),
hydrogen bromide (HBr), nitric oxide (NO), nitrogen dioxide
(NO2), and acrolein (CH2CHCHO).
In most common cases, a wide concentration range is covered by
an FTIR instrument. Generally, it is in the range from few μL/L to
thousands of μL/L for HCl, HBr, HF, SO2, NOx, HCN and up to few
percent for CO, CO2 and H2O. This list is only indicative and many
other species could be added [20]. Although not specifically
defined in this International Standard, as they were not
specifically studied in the SAFIR project [6], the method presented
is also suitable for analysis of other gaseous species, including
e.g. hydrogen fluoride (HF) and sulphur dioxide (SO2) with
appropriate sampling methods.
Calibration methods are provided in this International Standard.
Guidance is also given on the recommended cleaning, servicing and
operating checks and procedures to be carried out on the FTIR
instrument which is considered essential to maintain the instrument
in a suitable condition for use in fire effluent analysis.
Sampling is considered to be an integral part of the whole FTIR
measurement methodology and recommendations are made for the
design, maintenance and operation of suitable systems.
Conformance with this International Standard implies that:
• The sampling procedure used is in accordance with current
internationally accepted "best practice" for the applications
described.
•The analytical procedure has been carried out with due
regard to the restraints imposed by the nature of the fire effluent
atmosphere and the limitations of the FTIR methodology itself.
This International Standard only provides general
recommendations for the sampling and analysis of fire effluents,
based on best practice as determined from a wide variety of small-
and large-scale standard and ad hoc fire test studies. The Standard
may not be wholly applicable for use in specific published fire
test methods where FTIR may be specified as a requirement for
effluent sampling and analysis in that particular test. In these
cases the specific requirements for the sampling and analysis by
FTIR may be published within the standard test procedures and
should be followed. However if such specific requirements have not
been published, ISO 19702 may be used as a basis for acceptable
results.