M00000363
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ISO FDIS 10927 2018 Edition, March 31, 2018 Plastics - Determination of the molecular mass and molecular mass distribution of polymer species by matrix-assisted laser desorption/ ionization time-of-flight mass spectrometry (MALDI-TOF-MS)
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Availability date: 07/13/2021
Description / Abstract:
This document specifies a general method for determining the average molecular mass and molecular mass distribution of polymers (see Reference [1]) from 2 000 g ⋅ mol−1 to 20 000 g ⋅ mol−1 by matrixassisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF-MS).
The average molecular masses and molecular mass distributions are calculated from a calibration curve constructed using synthetic-polymer and/or biopolymer standards. This method is therefore classified as a relative method.
The method is not applicable to polyolefins or to polymers with a polydispersity 1,2