M00000142
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ISO 15064 3rd Edition, June 1, 2017 Plastics - Aromatic isocyanates for use in the production of polyurethanes - Determination of the isomer ratio in toluenediisocyanate (TDI)
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Availability date: 07/13/2021
Description / Abstract:
This document specifies methods for the measurement of toluene-2,6-diisocyanate in mixtures of the 2,4- and 2,6-isomers. Two methods based on infrared spectroscopy are used to give accurate results over a broad range of isomer concentrations. Method A is applicable to toluenediisocyanate (TDI) samples containing between 5 % and 95 % of the 2,6-isomer. Method B is applicable to TDI samples containing 0 % to 5 % of the 2,6-isomer. Both methods are based on the quantitative measurement of absorption bands arising from out-of-plane C−H deformation vibrations of the aromatic ring at 810 cm−1 and 782 cm−1 (12,3 μm and 13,8 μm).