M00001766
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ISO 20846 2nd Edition, October 1, 2011 Petroleum products — Determination of sulfur content of automotive fuels — Ultraviolet fluorescence method
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Availability date: 07/13/2021
Description / Abstract:
This International Standard specifies an ultraviolet (UV)
fluorescence test method for the determination of the sulfur
content of motor gasolines containing up to 3,7 % (m/m)
oxygen [including those blended with ethanol up to about 10 %
(V/V)], and of diesel fuels, including those containing up
to about 10 % (V/V) fatty acid methylester (FAME), having
sulfur contents in the range 3 mg/kg to 500 mg/kg. Other products
can be analysed and other sulfur contents can be determined
according to this test method, however, no precision data for
products other than automotive fuels and for results outside the
specified range have been established for this International
Standard. Halogens interfere with this detection technique at
concentrations above approximately 3 500 mg/kg.
NOTE 1 Some process catalysts used in petroleum and chemical
refining can be poisoned when trace amounts of sulfur-bearing
materials are contained in the feedstocks.
NOTE 2 This test method can be used to determine sulfur in
process feeds and can also be used to control sulfur in
effluents.
NOTE 3 For the purposes of this International Standard, the
terms "% (m/m)" and "% (V/V)" are used to
represent the mass fraction and the volume fraction of a material
respectively.
NOTE 4 Sulfate species in ethanol do not have the same
conversion factor of organic sulfur in ethanol. Nevertheless,
sulfates have a conversion factor close to that of organic
sulfur.
NOTE 5 It is preferable to check the nitrogen interference and
to take it into account, especially when sulfur content is measured
on diesel blended with cetane improver containing nitrogen. For
example, alkyl nitrate, as 2-ethyl hexyl nitrate (EHN), added as
cetane improver to diesel fuel shows an enhancing effect on sulfur
content that can range from 0 to 1,7 mg/kg when 2 000 mg/kg EHN is
added to diesel fuel containing 10 mg/kg sulfur.